The Birth-Time of the World and Other Scientific Essays Part 20

To fully answer the question which heads these lectures, we should go out into the populous solitudes (if the term be permitted) which lie beyond our system. It is well that there is now no time left to do so; for, in fact, there we can only dream dreams wherein the limits of the possible and the impossible become lost.

The marvel of the infinite number of stars is not so marvellous as the rationality that fain would comprehend them. In seeking other minds than ours we seek for what is almost infinitely complex and coordinated in a material universe relatively simple and heterogeneous. In our mental att.i.tude towards the great question, this fact must be regarded as fundamental.

I can only fitly close a discourse which has throughout weighed the question of the living thought against the unthinking laws of matter, by a paraphrase of the words

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of a great poet when he, in higher and, perhaps, more philosophic language, also sought to place the one in comparison with the other.[1]

Richter thought that he was--with his human heart unstrengthened--taken by an angel among the universe of stars.

Then, as they journeyed, our solar system was sunken like a faint star in the abyss, and they travelled yet further, on the wings of thought, through mightier systems: through all the countless numbers of our galaxy. But at length these also were left behind, and faded like a mist into the past. But this was not all. The dawn of other galaxies appeared in the void. Stars more countless still with insufferable light emerged. And these also were pa.s.sed. And so they went through galaxies without number till at length they stood in the great Cathedral of the Universe. Endless were the starry aisles; endless the starry columns; infinite the arches and the architraves of stars. And the poet saw the mighty galaxies as steps descending to infinity, and as steps going up to infinity.

Then his human heart fainted and he longed for some narrow cell; longed to lie down in the grave that he might hide from infinity.

And he said to the angel:

"Angel, I can go with thee no farther. Is there, then, no end to the universe of stars?"

[1] De Quincy in his _System of the Heavens_ gives a fine paraphrase of "Richter's Dream."

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Then the angel flung up his glorious hands to the heaven of heavens, saying "End is there none to the universe of G.o.d? Lo!

also there is no beginning."

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THE LATENT IMAGE [1]

My inclination has led me, in spite of a lively dread of incurring a charge of presumption, to address you princ.i.p.ally on that profound and most subtle question, the nature and mode of formation of the photographic image. I am impelled to do so, not only because the subject is full of fascination and hopefulness, but because the wide topics of photographic methods or photographic applications would be quite unfittingly handled by the president you have chosen.

I would first direct your attention to Sir James Dewar's remarkable result that the photographic plate retains considerable power of forming the latent image at temperatures approaching the absolute zero--a result which, as I submit, compels us to regard the fundamental effects progressing in the film under the stimulus of light undulations as other than those of a purely chemical nature. But few, if any, instances of chemical combination or decomposition are known at so low a temperature. Purely chemical actions cease, indeed, at far higher temperatures, fluorine being among the few bodies which still show

[1] Presidential address to the Photographic Convention of the United Kingdom, July, 1905. _Nature_, Vol. 72, p. 308.

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chemical activity at the comparatively elevated temperature of -180 C. In short, this result of Sir James Dewar's suggests that we must seek for the foundations of photographic action in some physical or intra-atomic effect which, as in the case of radioactivity or fluorescence, is not restricted to intervals of temperature over which active molecular vis viva prevails. It compels us to regard with doubt the role of oxidation or other chemical action as essential, but rather points to the view that such effects must be secondary or subsidiary. We feel, in a word, that we must turn for guidance to some purely photo-physical effect.

Here, in the first place, we naturally recall the views of Bose.

This physicist would refer the formation of the image to a strain of the bromide of silver molecule under the electric force in the light wave, converting it into what might be regarded as an allotropic modification of the normal bromide which subsequently responds specially to the attack of the developer. The function of the sensitiser, according to this view, is to r.e.t.a.r.d the recovery from strain. Bose obtained many suggestive parallels between the strain phenomena he was able to observe in silver and other substances under electromagnetic radiation and the behaviour of the photographic plate when subjected to long-continued exposure to light.

This theory, whatever it may have to recommend it, can hardly be regarded as offering a fundamental explanation. In the first place, we are left in the dark as to what

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the strain may be. It may mean many and various things. We know nothing as to the inner mechanism of its effects upon subsequent chemical actions--or at least we cannot correlate it with what is known of the physics of chemical activity. Finally, as will be seen later, it is hardly adequate to account for the varying degrees of stability which may apparently characterise the latent image. Still, there is much in Bose's work deserving of careful consideration. He has by no means exhausted the line of investigation he has originated.

Another theory has doubtless been in the minds of many. I have said we must seek guidance in some photo-physical phenomenon.

There is one such which preeminently connects light and chemical phenomena through the intermediary of the effects of the former upon a component part of the atom. I refer to the phenomena of photo-electricity.

It was ascertained by Hertz and his immediate successors that light has a remarkable power of discharging negative electrification from the surface of bodies--especially from certain substances. For long no explanation of the cause of this appeared. But the electron--the ubiquitous electron--is now known with considerable certainty to be responsible. The effect of the electric force in the light wave is to direct or a.s.sist the electrons contained in the substance to escape from the surface of the body. Each electron carries away a very small charge of negative electrification. If, then, a body is

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originally charged negatively, it will be gradually discharged by this convective process. If it is not charged to start with, the electrons will still be liberated at the surface of the body, and this will acquire a positive charge. If the body is positively charged at first, we cannot discharge it by illumination.

It would be superfluous for me to speak here of the nature of electrons or of the various modes in which their presence may be detected. Suffice it to say, in further connection with the Hertz effect, that when projected among gaseous molecules the electron soon attaches itself to one of these. In other words, it ionises a molecule of the gas or confers its electric charge upon it. The gaseous molecule may even be itself disrupted by impact of the electron, if this is moving fast enough, and left bereft of an electron.

We must note that such ionisation may be regarded as conferring potential chemical properties upon the molecules of the gas and upon the substance whence the electrons are derived. Similar ionisation under electric forces enters, as we now believe, into all the chemical effects progressing in the galvanic cell, and, indeed, generally in ionised solutes.

An experiment will best ill.u.s.trate the principles I wish to remind you of. A clean aluminium plate, carefully insulated by a sulphur support, is faced by a sheet of copper-wire-gauze placed a couple of centimetres away from it. The gauze is maintained at a high positive

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potential by this dry pile. A sensitive gold-leaf electroscope is attached to the aluminium plate, and its image thrown upon the screen. I now turn the light from this arc lamp upon the wire gauze, through which it in part pa.s.ses and shines upon the aluminium plate. The electroscope at once charges up rapidly.

There is a liberation of negative electrons at the surface of the aluminium; these, under the attraction of the positive body, are rapidly removed as ions, and the electroscope charges up positively.

Again, if I simply electrify negatively this aluminium plate so that the leaves of the attached electroscope diverge widely, and now expose it to the rays from the arc lamp, the charge, as you see, is very rapidly dissipated. With positive electrification of the aluminium there is no effect attendant on the illumination.

Thus from the work of Hertz and his successors we know that light, and more particularly what we call actinic light, is an effective means of setting free electrons from certain substances. In short, our photographic agent, light, has the power of expelling from certain substances the electron which is so potent a factor in most, if not in all, chemical effects. I have not time here to refer to the work of Elster and Geitel whereby they have shown that this action is to be traced to the electric force in the light wave, but must turn to the probable bearing of this phenomenon on the familiar facts of photography.

I a.s.sume that the experiment I have shown you is the most

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fundamental photographic experiment which it is now in our power to make.

We must first ask from what substances can light liberate electrons. There are many--metals as well as non-metals and liquids. It is a very general phenomenon and must operate widely throughout nature. But what chiefly concerns the present consideration is the fact that the haloid salts of silver are vigorously photo-electric, and, it is suggestive, possess, according to Schmidt, an activity in the descending order bromide, chloride, iodide. This is, in other words, their order of activity as ionisers (under the proper conditions) when exposed to ultra-violet light. Photographers will recognise that this is also the order of their photographic sensitiveness.

Another cla.s.s of bodies also concerns our subject: the special sensitisers used by the photographer to modify the spectral distribution of sensibility of the haloid salts, _e.g._ eosine, fuchsine, cyanine. These again are electron-producers under light stimulus. Now it has been shown by Stoletow, Hallwachs, and Elster and Geitel that there is an intimate connection between photo-electric activity and the absorption of light by the substance, and, indeed, that the particular wave-lengths absorbed by the substance are those which are effective in liberating the electrons. Thus we have strong reason for believing that the vigorous photo-electric activity displayed by the special sensitisers must be dependent upon their colour absorption. You will recognise that this is just

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the connection between their photographic effects and their behaviour towards light.

There is yet another suggestive parallel. I referred to the observation of Sir James Dewar as to the continued sensitiveness of the photographic film at the lowest attained extreme of temperature, and drew the inference that the fundamental photographic action must be of intra-atomic nature, and not dependent upon the vis viva of the molecule or atom. In then seeking the origin of photographic action in photo-electric phenomena we naturally ask, Are these latter phenomena also traceable at low temperatures? If they are, we are ent.i.tled to look upon this fact as a qualifying characteristic or as another link in the chain of evidence connecting photographic with photo-electric activity.

I have quite recently, with the aid of liquid air supplied to me from the laboratory of the Royal Dublin Society, tested the photo-sensibility of aluminium and also of silver bromide down to temperatures approaching that of the liquid air. The mode of observation is essentially that of Schmidt--what he terms his static method. The substance undergoing observation is, however, contained at the bottom of a thin copper tube, 5 cm. in diameter, which is immersed to a depth of about 10 cm in liquid air. The tube is closed above by a paraffin stopper which carries a thin quartz window as well as the sulphur tubes through which the connections pa.s.s. The air within is very carefully dried by phosphorus

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pentoxide before the experiment. The arc light is used as source of illumination. It is found that a vigorous photo-electric effect continues in the case of the clean aluminium. In the case of the silver bromide a distinct photo-electric effect is still observed. I have not had leisure to make, as yet, any trustworthy estimate of the percentage effect at this temperature in the case of either substance. Nor have I determined the temperature accurately. The latter may be taken as roughly about -150 C,

Sir James Dewar's actual measilrements afforded twenty per cent.

of the normal photographic effect at -180 C. and ten per cent.

at the temperature of -252.5 C.

With this much to go upon, and the important additional fact that the electronic discharge--as from the X-ray tube or from radium--generates the latent image, I think we are fully ent.i.tled to suggest, as a legitimate lead to experiment, the hypothesis that the beginnings of photographic action involve an electronic discharge from the light-sensitive molecule; in other words that the latent image is built up of ionised atoms or molecules the result of the photo-electric effect on the illuminated silver haloid, and it is upon these ionised atoms that the chemical effects of the developer are subsequently directed. It may be that the liberated electrons ionise molecules not directly affected, or it may be that in their liberation they disrupt complex molecules built up in the ripening of the