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Cooley's Cyclopaedia of Practical Receipts Volume Ii Part 178

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=PRU'NING= varies according to the kind of plant or tree operated on and the particular object in view, and its skilful performance must, therefore, greatly depend on the experience and knowledge of the gardener.

"In the operation of pruning, the shoots are cut off close to the buds, or at a distance not greater than the diameter of the branch to be cut off; because without the near proximity of a bud the wounds will not heal over.

In shoots which produce their buds alternately the cut is made at the back of the bud sloping from it, so that it may be readily covered by the bark in the same or in the following year; but in the case of branches where the buds are produced opposite each other, either one bud must be sacrificed or the branch must be cut off at right angles to its line of direction, which is most conveniently done with the pruning shears."

(Loudon.)

=PRUS'SIAN AL'KALI.= Ferrocyanide of pota.s.sium.



=PRUS'SIAN BLUE.= _Syn._ BERLIN BLUE, PARIS B., FERROCYANIDE OF IRON, PRUSSIATE OF I., CYANURET OF I. This is the well-known blue pigment of the shops.

_Prep._ 1. The crude but clear solution of ferrocyanide of pota.s.sium (blood lye) is precipitated by a mixed solution of alum, 2 parts, and green sulphate of iron, 1 part; the dingy greenish precipitate that falls gradually becomes blue by absorption of atmospheric oxygen, which is promoted by exposure and agitation of the liquor; as soon as it has acquired its full colour, the sediment is repeatedly washed with water, and is then drained, and dried, at first in a stove, but afterwards on chalk stones. Product large, but inferior in quality.

2. Repeatedly digest and wash the precipitate obtained by the above process in very dilute hydrochloric acid, and then in pure water; drain and dry it, as before. Superior.

3. (Paris blue.)--_a._ Neutralise the solution of ferrocyanide of pota.s.sium (blood lye) with dilute sulphuric acid, precipitate the liquid with a solution of any persalt or sesquisalt of iron (as the persulphate, nitrate, sesquichloride, or peracetate); well wash the precipitate with water, and dry it, as before. A very rich and intense colour.

_b._ (Hochstatter.) Crystallised ferrocyanide of pota.s.sium and green sulphate of iron, of each 6 parts, are each separately dissolved in water, 15 parts; after the admixture of the solutions, and frequent agitation, oil of vitriol, 1 part, and fuming hydrochloric acid, 24 parts, are stirred in; after some hours have elapsed a strained solution of chloride of lime, 1 part, dissolved in water, 80 parts, is gradually added, the addition being stopped as soon as an effervescence from the escape of chlorine is perceived; the whole is now left for 5 or 6 hours, when the precipitate is thoroughly washed in pure soft water, drained, and dried.

Or, instead of the above, the precipitate is at once washed in dilute nitric acid until its colour ceases to be improved by the process. The product is of the finest quality.

_Prop._ Insoluble in water and in dilute acids, except the oxalic, in solutions of which it dissolves freely when pure; oil of vitriol dissolves it to a white pasty ma.s.s, which is again precipitated of the usual blue colour by water; alkalies instantly decompose it, and so do red oxide of mercury and some other oxides when boiled with it; it burns in the air like tinder, leaving an ash of oxide of iron. It is not poisonous.

_Pur., &c._ The quality of Prussian blue may be estimated by the richness of its colour, and by the quant.i.ty of pota.s.sa or soda required to destroy this. If it effervesces with acids, it contains chalk; and if it forms a paste with boiling water, it is adulterated with starch. It is pure if, "after being boiled with dilute hydrochloric acid, ammonia throws down nothing from the filtered liquid." (Ph. L. 1836.) It is distinguished from indigo by exhibiting a coppery tint when broken, but which is removed by rubbing with the nail.

_Concluding Remarks._ The commercial Prussian blue is not pure ferrocyanide of iron, but a mixture of this salt with varying proportions of the ferricyanide of iron and pota.s.sium, which also has a fine deep blue colour. The object in employing alum is to prevent or lessen the precipitation of oxide of iron by the free alkali in the blood lye, but a portion of alumina is in consequence thrown down with the blue, and tends to render it paler and increase the product. The quant.i.ty of alum employed may be varied according to the shades of the intended blue. Samples containing this contamination must not be employed medicinally. (See page 324.)

=Prussian Blue, Sol'uble.= _Prep._ 1. (BASIC PRUSSIAN BLUE.) By adding a solution of protosulphate of iron to a solution of ferrocyanide of pota.s.sium; a bluish-white precipitate, turning dark blue by free exposure, is formed, which, after it has acquired this colour, is washed until it begins to dissolve in the water, and colour it blue; it is then either collected and dried, or is at once dissolved in pure water. This variety is not precipitated from its solution by alcohol.

2. (FERROCYANIDE OF POTa.s.sIUM AND IRON.) By precipitating a solution of a sesquisalt or persalt of iron (as the persulphate, pernitrate, peracetate, or sesquichloride) with a stronger solution of ferrocyanide of pota.s.sium, so that the latter may be in considerable excess. A blue precipitate is formed, which is treated as before. This variety is precipitated by alcohol. Both are freely soluble in pure water, but not in water which has the slightest saline contamination. Hence it is that lengthened exposure to the atmosphere and the use of the common steel pen causes the gradual precipitation of this substance from its solution when used as ink. See WRITING FLUIDS.

=PRU"SSIC ACID.= See HYDROCYANIC ACID.

=PSEU'DO-MOR'PHIA.= A substance of little importance, occasionally found in opium. It differs from morphine chiefly in not decomposing iodic acid.

It is said to contain nitrogen.

=PTIS'AN.= _Syn._ PTISANA, L. A decoction made of pearl barley, liquorice, raisins, and other like vegetable matters, either alone or so slightly medicated as to be taken as a common drink in fevers, catarrhs, &c. Those retained in English pharmacy have been already noticed. The French physicians often employ this form of medicine. The 'tisanes' of the P.

Cod. are numerous. See DECOCTION, INFUSION, JULEP, TISANE, &c.

=PTY'ALIN.= A peculiar animal matter, a.n.a.logous to diastase, obtained from the saliva. It is soluble in water, but insoluble in alcohol.

Mialhe named ptyalin "animal diastase," and regarded it as the princ.i.p.al agent in effecting the digestion of starchy foods, by converting them into soluble glucose. One part of ptyalin, according to Mialhe, was capable of transforming 800 parts of insoluble starch into sugar. It has been computed that the average daily secretion of ptyalin by an adult amounts to 116 grains. It very quickly decomposes, and in properties somewhat resembles sodic alb.u.minate.

=PUCHA PAT.= _Syn._ PATCHOULI. Pucha pat is the dried foliaceous tops of _Pogostemon Patchouli_, an Indian species of _l.a.b.i.atae_. It is much used in perfumery, particularly for making sachets; but its odour, although very durable, is not so agreeable as that of many other substances, unless it is combined with lavender, bergamot, ambergris, musk, or some other like perfume.

=PUD'DINGS.= The instructions given under CAKES, PIES, &c., will be found, with some slight modifications, also to apply to puddings, and, therefore, need not be repeated here. Soyer tells us that every sort of pudding, if sweet or savory, is preferably dressed in a basin instead of in a cloth.

If boiled in a basin the paste receives all the nutriment of the materials, which, if boiled in a cloth, are dissolved out by the water, when by neglect it ceases boiling. To cause them to turn well out, the inside of the basin should be thoroughly 'larded' or rubbed with b.u.t.ter.

In the preparation of meat puddings the first and most important point is never to use any meat that is tainted; for in pudding, above all other dishes, it is least possible to disguise it by the confined progress which the ingredients undergo. The gradual heating of the meat, which alone would accelerate decomposition, will cause the smallest piece of tainted meat to contaminate all the rest. Be particular, also, that the suet and fat are not rancid, ever remembering the grand principle that everything which gratifies the palate nourishes."

"A pudding cloth, however coa.r.s.e, ought never to be washed with soap; it should be simply dried as quickly as possible, and kept dry and free from dust, and in a drawer or cupboard free from smell." (Soyer.)

=PUD'DLING.= See IRON.

=PULMONI'TIS.= Inflammation of the lungs.

=PULP.= _Syn._ PULPA, L. The softer parts of plants, more particularly of fruits, separated from the fibrous and harder portions.

"Pulpy fruits, if they be unripe, or ripe and dried, are to be placed in a damp situation until they become soft; then the pulp is to be pressed out through a hair sieve; afterwards it is to be boiled with a gentle heat, frequently stirring; and finally, the (excess of) water is to be evaporated in a water bath, until the pulp acquire proper consistence.

"Press the pulpy fruits which are ripe and fresh through a hair sieve, without boiling them." (Ph. L. 1836.)

=PULVERISA'TION.= The reduction of any substance to dust or powder.

On the small scale, pulverisation is usually performed by means of a pestle and mortar; on the large scale, by stamping, grinding or cutting the substance in a mill. A few soft substances, as carbonate of magnesia, carbonate of lead, &c., may be pulverised by simply rubbing them through a fine sieve, placed over a sheet of paper; whilst many hard, gritty substances can only be reduced to fine powder by porphyrisation or levigation. Elutriation, or 'washing over,' is adopted for several substances, as chalk, antimony, &c., which are required to be reduced to fine powder on the large scale. For some articles which are very tough, fibrous, or resisting, a rasp or file is employed. Whichever of these methods is adopted, the body to be powdered must be very dry, and where spontaneous drying is insufficient, artificial desiccation in a stove or oven, gently heated, is employed. To facilitate this, the substance should be first cut into pieces or crushed small. On the other hand, a few substances, as rice, sago, nux vomica, and St Ignatius's bean, are often soaked in water, or steamed, before being further operated on. Whenever a substance cannot be dried completely, without an alteration of its properties, an intermedium is had recourse to, by which the moisture may be absorbed, or its state of aggregation modified. Thus, sugar is employed in pulverising civet, musk, nutmeg, and vanilla. When camphor is to be pulverised, the addition of a very small quant.i.ty of alcohol renders the operation easy. In other cases the intermedium is of so hard a nature as to a.s.sist in breaking down the substance to be powdered; thus, gold leaf is reduced to powder by rubbing it with sulphate of pota.s.sa, and afterwards removing this last by means of water. Fusible metals, as zinc and tin, are powdered by pouring them into a mortar, and stirring them rapidly whilst cooling; or, by briskly agitating them, in the melted state, in a wooden box covered with chalk or whiting. Phosphorus is powdered by melting it in urine or lime water, and then shaking the bottle until its contents have become quite cold. Gla.s.s, quartz, and silicated stones, require to be heated red hot, and in this state to be thrown into cold water, by which they become sufficiently friable to admit of pulverisation. Many salts which are reduced to fine powder with very great difficulty, and do not dissolve in spirit of wine, are easily obtained in a pulverulent form, by agitating their concentrated aqueous solution with a considerable quant.i.ty of rectified spirit; the disengaged fine crystallised powder may then be dried, and further divided by trituration.

Pota.s.sio tartrate of antimony may be advantageously thus treated. A large number of salts, including nitre, sal ammoniac, and carbonate of potash, may also be reduced to powder by keeping their solutions in a state of constant and violent agitation during their rapid evaporation.

The following rules should be observed in the preparation of powders:--

1. If possible, perfectly dry articles should alone be operated on, and only in dry weather.

2. The nature of the mortar, and the mode of operating, should be adapted to the nature of the substance. Thus, woods and barks should be pulverised in an iron mortar; sugar, alum, and nitre, in one of marble or wedgwood-ware; and corrosive sublimate, only in one of gla.s.s.

3. The mortar should be provided with a cover, to prevent loss and annoyance to the operator. If much powder escapes, or if it is dangerous or disagreeable when breathed, or if the substance is rare or costly, the mortar should be covered with a skin of leather, to which the pestle is attached, so that the latter may be freely moved without causing the slightest opening for the escape of the dust occasioned by the process.

When aloes or gamboge is powdered, a few drops of olive oil are commonly added with the same intention.

4. The pulverised portions should be separated from time to time by aid of a sieve, the coa.r.s.er particles being returned to the mortar to be again beaten and triturated; and this alternate pulverisation and sifting is to be repeated until the process is complete.

=PUM'ICE STONE.= _Syn._ PUMEX, LAPIS PUMICEUS, L. PUMICIS, L. Found in the neighbourhood of volcanoes. Used, in the solid form, to polish wood, paint, &c.; also, when pulverised, as a polishing powder for gla.s.s, bone, ivory, marble, metals, &c.

=PUMP FOR USE IN CHEMICAL, PAPER, and other Works.= The Perreaux Pump Valve is made of vulcanised india rubber, and is of the form of the valves in the human body. It is of the greatest, and perhaps the really only valuable improvement in valves applicable, equally, to the common hand or jack pump, and the most elaborate mechanical combinations for raising water.

The valve may be taken as the key of the pump; a perfect valve renders an indifferent pump a valuable and effective machine, whereas an imperfect valve, in an otherwise excellently constructed pump, renders it practically useless.

The pump which Simon the tanner, of Joppa, used for pumping his pits, nearly two thousand years ago, may be taken as the type of the common hand pump in use to this day. Various mechanical improvements have been made in its form and construction, but, practically, and effectively, the only real and valuable improvement is the Perreaux valve, now under consideration.

Constructed of a flexible material, and made in form, as nearly as may be, to the valves of the human body, they may be said to be automatic in their action, or self acting; upon the pump being actuated, the least motion of the pump ensuring a corresponding action of the valve, and the most rapid action of the pump, being equally responded to by the pulsation of the valves.

Although the most perfect valves for pumping clear water, because, what is mechanically termed the duty of the pump is complete, in other words, the quant.i.ty displaced is discharged, absolutely without loss, yet their most valuable feature is that they pump semi-fluids equally well as clear water.

For the pulps and stuffs in paper mills, for bleaches, dyes, and corrosive liquors, for liquid manures and other such semi-fluids, they stand alone, they are absolutely unchokable.

Used in conjunction with cylinders or barrels made of toughened gla.s.s, they form the most perfect pump where the fluid to be raised is of a caustic or corrosive nature, and where the fluid would be destructive to or destroyed by its action upon metals, such for example as the caustic bleach used in the manufacture of paper, &c. See VALVES.

=PUNCH.= An acidulous, intoxicating beverage, composed of water sweetened with sugar, with a mixture of lemon juice and spirit, to which some aromatic, as nutmeg, mace, or cinnamon, is occasionally added. Wine is sometimes subst.i.tuted for spirit. It is much less drunk than formerly. Rum punch is the most popular amongst sailors, who are now the princ.i.p.al consumers of this beverage.

_Prep._ 1. Juice of 3 or 4 lemons; yellow peel of 1 lemon; lump sugar, 3/4 lb.; boiling water, 3-1/2 pints; infuse 1/2 an hour, strain, and add, of bitter ale, 1/2 pint; rum and brandy, of each 3/4 to 1 pint (or rum alone, 1-1/2 to 2 pints). More hot water and sugar may be added if the punch is desired either weaker or sweeter.

2. (COLD PUNCH.) From arrack, port wine, and water, of each 1 pint; juice of 4 lemons; white sugar, 1 lb.

3. (GIN PUNCH.) From the yellow peel of 1/2 a lemon; juice of 1 lemon; strongest gin, 3/4 pint; water, 1-3/4 pint; sherry, 1 gla.s.sful.

4. (ICED PUNCH.) From champagne or Rhenish wine, 1 quart; arrack, 1 pint; juice of 6 lemons; yellow peel of 3 lemons; white sugar, 1 lb.; soda water, 1 or 2 bottles; to be iced as cream.

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Cooley's Cyclopaedia of Practical Receipts Volume Ii Part 178 summary

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