Conversations on Chemistry Part 63

So it has, indeed! And do the other alkalies produce a similar effect?

MRS. B.

Exactly the same. --We may now proceed to SODA, which, however important, will detain us but a very short time; as in all its general properties it very strongly resembles potash; indeed, so great is their similitude, that they have been long confounded, and they can now scarcely be distinguished, except by the difference of the salts which they form with acids.

The great source of this alkali is the sea, where, combined with a peculiar acid, it forms the salt with which the waters of the ocean are so strongly impregnated.

EMILY.

Is not that the common table salt?

MRS. B.

The very same; but again we must postpone entering into the particulars of this interesting combination, till we treat of the neutral salts.

Soda may be obtained from common salt; but the easiest and most usual method of procuring it is by the combustion of marine plants, an operation perfectly a.n.a.logous to that by which potash is obtained from vegetables.

EMILY.

From what does soda derive its name?

MRS. B.

From a plant called by us _soda_, and by the Arabs _kali_, which affords it in great abundance. Kali has, indeed, given its name to the alkalies in general.

CAROLINE.

Does soda form gla.s.s and soap in the same manner as potash?

MRS. B.

Yes, it does; it is of equal importance in the arts, and is even preferred to potash for some purposes; but you will not be able to distinguish their properties till we examine the compound salts which they form with acids; we must therefore leave soda for the present, and proceed to AMMONIA, or the VOLATILE ALKALI.

EMILY.

I long to hear something of this alkali; is it not of the same nature as hartshorn?

MRS. B.

Yes, it is, as you will see by-and-bye. This alkali is seldom found in nature in its pure state; it is most commonly extracted from a compound salt, called _sal ammoniac_, which was formerly imported from _Ammonia_, a region of Libya, from which both these salts and the alkali derive their names. The crystals contained in this bottle are specimens of this salt, which consists of a combination of ammonia and muriatic acid.

CAROLINE.

Then it should be called _muriat of ammonia_; for though I am ignorant what muriatic acid is, yet I know that its combination with ammonia cannot but be so called; and I am surprised to see sal ammoniac inscribed on the label.

MRS. B.

That is the name by which it has been so long known, that the modern chemists have not yet succeeded in banishing it altogether; and it is still sold under that name by druggists, though by scientific chemists it is more properly called muriat of ammonia.

CAROLINE.

Both the popular and the common name should be inscribed on labels--this would soon introduce the new nomenclature.

EMILY.

By what means can the ammonia be separated from the muriatic acid?

MRS. B.

By chemical attractions; but this operation is too complicated for you to understand, till you are better acquainted with the agency of affinities.

EMILY.

And when extracted from the salt, what kind of substance is ammonia?

MRS. B.

Its natural form, at the temperature of the atmosphere, when free from combination, is that of gas; and in this state it is called _ammoniacal gas_. But it mixes very readily with water, and can be thus obtained in a liquid form.

CAROLINE.

You said that ammonia was more complicated in its composition than the other alkalies; pray of what principles does it consist?

MRS. B.

It was discovered a few years since, by Berthollet, a celebrated French chemist, that it consisted of about one part of hydrogen to four parts of nitrogen. Having heated ammoniacal gas under a receiver, by causing the electrical spark to pa.s.s repeatedly through it, he found that it increased considerably in bulk, lost all its alkaline properties, and was actually converted into hydrogen and nitrogen gases; and from the latest and most accurate experiments, the proportions appear to be, one volume of nitrogen gas to three of hydrogen gas.

CAROLINE.

Ammonia, therefore, has not, like the two other alkalies, a metallic basis?

MRS. B.

It is believed it has, though it is extremely difficult to reconcile that idea with what I have just stated of its chemical nature. But the fact is, that although this supposed metallic basis of ammonia has never been obtained distinct and separate, yet both Professor Berzelius, of Stockholm, and Sir H. Davy, have succeeded in forming a combination of mercury with the basis of ammonia, which has so much the appearance of an amalgam, that it strongly corroborates the idea of ammonia having a metallic basis.* But these theoretical points are full of difficulties and doubts, and it would be useless to dwell any longer upon them.

Let us therefore return to the properties of volatile alkali. Ammoniacal gas is considerably lighter than oxygen gas, and only about half the weight of atmospherical air. It possesses most of the properties of the fixed alkalies; but cannot be of so much use in the arts on account of its volatile nature. It is, therefore, never employed in the manufacture of gla.s.s, but it forms soap with oils equally as well as potash and soda; it resembles them likewise in its strong attraction for water; for which reason it can be collected in a receiver over mercury only.

[Footnote *: This amalgam is easily obtained, by placing a globule of mercury upon a piece of muriat, or carbonat of ammonia, and electrifying this globule by the Voltaic battery. The globule instantly begins to expand to three or four times its former size, and becomes much less fluid, though without losing its metallic l.u.s.tre, a change which is ascribed to the metallic basis of ammonia uniting with the mercury. This is an extremely curious experiment.]

CAROLINE.

I do not understand this?

MRS. B.

Do you recollect the method which we used to collect gases in a gla.s.s-receiver over water?

CAROLINE.

Perfectly.