Conversations on Chemistry Part 31

CAROLINE.

Perfectly. This, then, is pure oxygen gas; what a pity it should be lost! Could you not preserve it?

MRS. B.

We shall collect it in this receiver. --For this purpose, you observe, I first fill it with water, in order to exclude the atmospherical air; and then place it over the bubbles that issue from the retort, so as to make them rise through the water to the upper part of the receiver.

EMILY.

The bubbles of oxygen gas rise, I suppose, from their specific levity?

MRS. B.

Yes; for though oxygen forms rather a heavy gas, it is light compared to water. You see how it gradually displaces the water from the receiver.

It is now full of gas, and I may leave it inverted in water on this shelf, where I can keep the gas as long as I choose, for future experiments. This apparatus (which is indispensable in all experiments in which gases are concerned) is called a water-bath.

CAROLINE.

It is a very clever contrivance, indeed; equally simple and useful. How convenient the shelf is for the receiver to rest upon under water, and the holes in it for the gas to pa.s.s into the receiver! I long to make some experiments with this apparatus.

MRS. B.

I shall try your skill that way, when you have a little more experience.

I am now going to show you an experiment, which proves, in a very striking manner, how essential oxygen is to combustion. You will see that iron itself will burn in this gas, in the most rapid and brilliant manner.

CAROLINE.

Really! I did not know that it was possible to burn iron.

EMILY.

Iron is a simple body, and you know, Caroline, that all simple bodies are naturally positive, and therefore must have an affinity for oxygen.

MRS. B.

Iron will, however, not burn in atmospherical air without a very great elevation of temperature; but it is eminently combustible in pure oxygen gas; and what will surprise you still more, it can be set on fire without any considerable rise of temperature. You see this spiral iron wire--I fasten it at one end to this cork, which is made to fit an opening at the top of the gla.s.s-receiver. (PLATE VII. Fig. 4.)

EMILY.

I see the opening in the receiver; but it is carefully closed by a ground gla.s.s-stopper.

MRS. B.

That is in order to prevent the gas from escaping; but I shall take out the stopper, and put in the cork, to which the wire hangs. --Now I mean to burn this wire in the oxygen gas, but I must fix a small piece of lighted tinder to the extremity of it, in order to give the first impulse to combustion; for, however powerful oxygen is in promoting combustion, you must recollect that it cannot take place without some elevation of temperature. I shall now introduce the wire into the receiver, by quickly changing the stoppers.

CAROLINE.

Is there no danger of the gas escaping while you change the stoppers?

MRS. B.

Oxygen gas is a little heavier than atmospherical air, therefore it will not mix with it very rapidly; and, if I do not leave the opening uncovered, we shall not lose any----

CAROLINE.

Oh, what a brilliant and beautiful flame!

EMILY.

It is as white and dazzling as the sun! --Now a piece of the melted wire drops to the bottom: I fear it is extinguished; but no, it burns again as bright as ever.

MRS. B.

It will burn till the wire is entirely consumed, provided the oxygen is not first expended: for you know it can burn only while there is oxygen to combine with it.

CAROLINE.

I never saw a more beautiful light. My eyes can hardly bear it! How astonishing to think that all this caloric was contained in the small quant.i.ty of gas and iron that was enclosed in the receiver; and that, without producing any sensible heat!

CAROLINE.

How wonderfully quick combustion goes on in pure oxygen gas! But pray, are these drops of burnt iron as heavy as the wire was before?

MRS. B.

They are even heavier; for the iron, in burning, has acquired exactly the weight of the oxygen which has disappeared, and is now combined with it. It has become an oxyd of iron.

CAROLINE.

I do not know what you mean by saying that the oxygen has _disappeared_, Mrs. B., for it was always invisible.

MRS. B.

True, my dear; the expression was incorrect. But though you could not see the oxygen gas, I believe you had no doubt of its presence, as the effect it produced on the wire was sufficiently evident.

CAROLINE.

Yes, indeed; yet you know it was the caloric, and not the oxygen gas itself, that dazzled us so much.

MRS. B.

You are not quite correct in your turn, in saying the caloric dazzled you; for caloric is invisible; it affects only the sense of feeling; it was the light which dazzled you.

CAROLINE.

True; but light and caloric are such constant companions, that it is difficult to separate them, even in idea.

MRS. B.